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通过N-(4-吡啶基)苯甲酰胺(NPBA)与金属离子反应,制备了两个三维超分子配合物[Zn(NPBA)2Cl2]和[Cd(NPBA)2(NO3)2(H2O)2].通过元素分析、红外光谱以及X-ray单晶衍射测试对它们的分子结构进行了表征.结果表明,通过分子间氢键、π-π堆积力和分子间作用力,形成了三维的超分子结构,并进一步研究了它们的热稳定性.
Abstract：Two 3D supramolecules,[Zn(NPBA)2Cl2] and [Cd(NPBA)2(NO3)2(H2O)2],were produced by the reaction of N-(4-pyridyl)benzamide(NPBA) with metal ions,and structurally characterized by EA,IR and single-crystal X-ray diffraction.Hydrogen bonds and weak-stacking provided the additional force of stability for the 3D solid-state structures.The thermal properties of the complexes were investigated under ail.
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基本信息:
中图分类号:O626
引用信息:
[1]李子峰,贾宏亮,王宝兰,等.基于吡啶酰胺配体的超分子配合物的合成、结构及性质[J],2012,44(04):93-97+108.
基金信息:
国家自然科学基金资助项目,编号21071127;; 河南省教育厅自然科学基金资助项目,编号12A150024