二茂铁丙烯酸和2,2′-联吡啶的混配合物的合成与表征Syntheses and Characterization of Heterocomplexes of 3 Ferrocenylacrylic Acid and 2,2′ Dipyridine
张鸿云,雷静,吴庆安,陈佩琨,张郁松
摘要(Abstract):
合成了二茂铁丙烯酸和2 ,2′联吡啶与 Zn( Ⅱ) , Cd( Ⅱ) , Hg( Ⅱ) ,及 Pb( Ⅱ) 的混配合物,用元素分析, I R, U V,1 H N M R,摩尔电导和热分析确定了这些配合物的组成为:( C5 H5 Fe C5 H4 C H= C H C O O)2 M( C5 H4 N)2
关键词(KeyWords): 二茂铁丙烯酸;2,2′联吡啶;混配合物
基金项目(Foundation): 国家自然科学基金
作者(Author): 张鸿云,雷静,吴庆安,陈佩琨,张郁松
参考文献(References):
- [1] 段迎春,夏旭兵,朱龙根等.二茂铁基多核配合物的合成及猝灭 Ru(bpy)2 +3 发光过程研究,高等化学学报,1992 ,13(5) ,576
- [2] Masaru Sato . A Simple Modification of Vilsmeier Method for the Preparation of Form ylferrocene . Bulletin Chem Soc Japan ,1968 ,41 :252
- [3] Broadhead G D. Ferrocene Derivatices , Part V. Ferrocenealdehyde . J Chem Soc, 1958 ,85 :650
- [4] Mannhas B S, Trikna A K. Relationships between the Directon of Shifts in the Carbonoxygen Stretching Frequencies of Carboxylato Co mplexes and the Type of Carboxylate Coordination . J Indian Chem Soc ,1982 ,59 ,315
- [5] Rosenblum M , Santer J O and Howells W Glenn . The Che mistry and Structure of Ferrocene . V Ⅲ. Interannutar Resonance and the Mechanism of Electrophilic Substitution . J Am Chem Soc ,1963 ,85 ,1450